Everyones hair is different, but some will benefit from lower heat than others. Typically the thicker, or coarser the hair is, the higher heat it can handle, hence why the SpeedStyle's higher 110°C temperature will be better suited for thicker hair. Conversely the FlexStyle's temperatures of 55°C - 95°C will be less damaging to thin, and damaged hair.
These rules aren't absolute of course, and both styling temperatures are low enough that neither should cause lasting damage. However the super low temps of the FlexStyle may prove to be too low for thicker hair types. If you tend to crank up the temp on your straightener, then you'll probably want to opt for the SpeedStyle for a better all around device.
It is also worth noting that the SpeedStyle has ionic technology that will help smooth out friziness, but the FlexStyle doesn't.